Enthalpy of Combustion

  • In combustion processes, reactants are consumed to form products and energy is released.
  • This energy comes from a rearrangement of chemical bonds in the reactants to form the products.
  • The standard enthalpy of formation, ∆hoi , quantifies the chemical bond energy of a chemical species at standard conditions.
  • The enthalpy of formation of a substance is the energy needed for the formation of that substance from its constituent elements at STP conditions (25°C and 1 atm).
  • The ‘absolute’ or ‘total’ enthalpy = enthalpy of formation + sensible enthalpy
  • One way to determine the enthalpy of formation of a species is to use a constant pressure flow reactor
  • When phase change is encountered, the total enthalpy needs to include the latent heat

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